Electrical Conductivity Change of Polyaniline-Dodecyl Benzene Sulfonic Acid Complex with Temperature

1996 ◽  
Vol 7 (7) ◽  
pp. 599-603 ◽  
Author(s):  
Seok Kim ◽  
Jang Myoun Ko ◽  
In Jae Chung
Keyword(s):  
Electrical Conductivity ◽  
Sulfonic Acid ◽  
Acid Complex ◽  
Benzene Sulfonic Acid ◽  
Conductivity Change ◽  
Dodecyl Benzene Sulfonic Acid ◽  
Electrical Conductivity Change

The Morphology, Structure and Electrical Properties of Polypyrrole Nanofibers via Electrospinning

2012 ◽  
Vol 616-618 ◽  
pp. 1675-1679
Author(s):  
Lei Zhao ◽  
Xing Xiang Zhang ◽  
Ning Wang
Keyword(s):  
Electrical Conductivity ◽  
Electrical Properties ◽  
Sodium Salt ◽  
Sulfonic Acid ◽  
Benzene Sulfonic Acid ◽  
One Dimensional ◽  
Acid Sodium Salt ◽  
Dodecyl Benzene Sulfonic Acid ◽  
Sulfosuccinate Sodium ◽  
Sulfonic Acid Sodium Salt

One-dimensional nanostructured polypyrrole (PPy) nanofibers were electrospun using a solution of PPy/polyvinyl alcohol (PVA); and PVA was used as the carrier in order to improve processability of PPy. In order to improve the performance of nanofibers, PPy were chemically synthesized by using different dopants, such as toluene sulfonate (TSNa), dodecyl-benzene sulfonic acid sodium salt (DBSNa), dodecyl sulfonic acid sodium salt (DSNa) and di-(2-ethylhexyl) sulfosuccinate sodium salt (DEHS). The morphology, structure and electrical conductivity of the fabricated nanofibers was investigated using SEM, FTIR and four-probe method, respectively. The results show that the diameters of doped PPy/PVA nanofibers are in the range of 50-190 nm. The electrical conductivity of the obtained doped PPy/PVA nanofibers was about 161-222 S/cm. DEHS doped PPy can not only make the obtained PPy be soluble in some organic solvents, but also improve the electrical conductivity of nanofibers when it is compared with that of TSNa, DSNa, DBSNa as dopants.

Characterization of Polyvinyl Alcohol-Polyaniline Blend Films

2010 ◽  
Vol 44-47 ◽  
pp. 2191-2194 ◽  
Author(s):  
Wang Xi Zhang
Keyword(s):  
Electrical Conductivity ◽  
Polyvinyl Alcohol ◽  
Sulfonic Acid ◽  
Emeraldine Base ◽  
Scanning Electronic Microscopy ◽  
Benzene Sulfonic Acid ◽  
X Ray ◽  
Blend Films ◽  
Dodecyl Benzene Sulfonic Acid

In this study a solution-blend method is adopted to prepare conductive polyvinyl alcohol (PVA) and polyaniline doped with dodecyl benzene sulfonic acid (PVA/PANI-DBSA) blend films. Emeraldine base (EB)-type polyaniline (PANI) is dissolved in N-methyl-2-pyrrolidinone (NMP) and then blended with PVA/dodecyl benzene sulfonic acid (DBSA) solution by various amounts. The morphological structures and characterized of the films were observed via scanning electronic microscopy (SEM), thermogravimetric analysis (TGA) and X-ray powder diffraction (XRD). Electrical properties of the blends were characterized by means of electrical conductivity measurements. It is found that the electrical conductivity and the thermal degradation onset temperature of the PVA/PANI-DBSA blend film are increased as the amount of PANI-DBSA is increased.

Localized polarons in in situ synthesized polyaniline nanocomposite improve the morphology and the thermal and electrical conductivity

RSC Advances ◽  
2016 ◽  
Vol 6 (116) ◽  
pp. 115074-115084 ◽  
Author(s):  
M. Niranjana ◽  
L. Yesappa ◽  
S. P. Ashokkumar ◽  
H. Vijeth ◽  
S. Raghu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Cobalt Oxide ◽  
Chemical Reaction ◽  
Sulfonic Acid ◽  
Benzene Sulfonic Acid ◽  
Reaction Method ◽  
Dodecyl Benzene Sulfonic Acid ◽  
Chemical Reaction Method ◽  
Polyaniline Nanocomposite

This paper reports the localized polarons improves the morphology, thermal and electrical conductivity of dodecyl benzene sulfonic acid (DBSA) surfactant based polyaniline (PANI) – cobalt oxide (Co3O4) nano have synthesized by using in situ chemical reaction method.

scholarly journals Effect of Rejuvenator Containing Dodecyl Benzene Sulfonic Acid (DBSA) on Physical Properties, Chemical Components, Colloidal Structure and Micro-Morphology of Aged Bitumen

Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1476 ◽  
Author(s):  
Dongliang Kuang ◽  
Zhou Ye ◽  
Lifeng Yang ◽  
Ning Liu ◽  
Zaihong Lu ◽  
...  
Keyword(s):  
Thin Film ◽  
Physical Properties ◽  
Sulfonic Acid ◽  
Chemical Components ◽  
Structure Transformation ◽  
Colloidal Structure ◽  
Benzene Sulfonic Acid ◽  
Oven Test ◽  
Dodecyl Benzene Sulfonic Acid ◽  
Micro Morphology

DBSA was used as a solubilizer together with conventional rejuvenator (CR) to produce a solubilized rejuvenator (SR), two kinds of aged bitumen involving TFOT aged bitumen and PAV aged bitumen were obtained by thin film oven test (TFOT) and pressurized aging vessel (PAV), respectively. Effects of CR and SR on the physical properties, chemical components, colloidal structure and micro-morphology of TFOT aged bitumen and PAV aged bitumen were investigated. Testing results of physical properties and chemical components indicated that CR and SR can replenish aged bitumen with necessary aromatics, TFOT aged bitumen that chemical component variation deteriorates its physical properties. With regard to PAV aged bitumen, of which the performance attenuation lies in chemical components variation and colloidal structure transformation, even if the content of CR reached up to 10 wt %, the regenerated bitumen cannot meet the regeneration requirement yet due to its definite influence on colloidal structure transformation, comparatively, sulfonic group in SR can react with the superficial atoms of asphaltenes to reform a solvation layer to facilitate the colloidal structure transformation of PAV aged bitumen, performance and beelike structure of regenerated PAV aged with bitumen with 10 wt % SR were approximated to that of virgin bitumen.

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